|
|
(2E,6E)-farnesyl_diphosphate <=> 5-epiaristolochene + diphosphate
|
4.2.3.61
5-epiaristolochene synthase
4.2.3.9
aristolochene synthase
|
–
–
|
MK
|
| |
BRENDA:
BR49543
KEGG:
R09574
MetaCyc:
RXN-4781
|
|
|
|
5-epiaristolochene + 2 reduced_flavodoxin + 2 O2 <=> capsidiol + 2 flavin + 2 H2O
|
1.14.14.149
5-epiaristolochene 1,3-dihydroxylase
|
–
|
K
|
| |
BRENDA:
BR49418
KEGG:
R09573
|
|
|
|
5-epiaristolochene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> capsidiol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.149
5-epiaristolochene 1,3-dihydroxylase
|
–
|
|
| |
MetaCyc:
RXN-11908
|
|
|
|
5-epiaristolochene + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1beta-hydroxy-5-epiaristolochene + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-4801
|
|
|
|
5-epiaristolochene + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-deoxycapsidiol + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-4802
|
|
|
|
5-epiaristolochene + 3 reduced_flavodoxin + 3 O2 <=> 2beta-hydroxy-epiaristolochene + 1beta-hydroxy-5-epiaristolochene + 1-deoxycapsidiol + 3 flavin + 3 H2O
|
1.14.14.151
premnaspirodiene oxygenase
|
–
|
|
| |
BRENDA:
BS414152
|
|
|
|
5-epiaristolochene + reduced_flavodoxin + O2 <=> 1beta-hydroxy-5-epiaristolochene + flavin + H2O
|
1.14.14.149
5-epiaristolochene 1,3-dihydroxylase
|
–
|
|
| |
BRENDA:
BS413230
|
|
|
|
5-epiaristolochene + reduced_flavodoxin + O2 <=> 1-deoxycapsidiol + flavin + H2O
|
1.14.14.149
5-epiaristolochene 1,3-dihydroxylase
|
–
|
|
| |
BRENDA:
BS413232
|
|
|
|
2 NADPH + 2 H+ + 2 O2 + 5-epiaristolochene <=> 2 H2O + 2 NADP+ + capsidiol
|
1.14.14.149
5-epiaristolochene 1,3-dihydroxylase
|
–
|
|
| |
SABIO-RK:
7085
|
|
